大环配体
- 网络macrocyclic ligand
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含联吡啶单元大环配体的合成
Syntheses of Macrocyclic Ligand Containing Bipyridine Subunit
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单N-乙酸取代N2O2大环配体及其过渡金属配合物的合成与性质的研究
Synthesis and characterization of a new mono-N-acetic acid substituted N_2O_2 macrocycle and its complexes with transition metals
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上述大环配体和各种配合物均经元素分析、IR、~1HNMR、MS等证实了它们的结构和组成。
All these macrocyclic compounds and complexes were identified by elemental analysis and spectral analysis ( IR , ~ 1HNMR , MS ) .
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两类新型含硫手性大环配体的合成
The Synthesis of Two Series Novel Sulfur containing Chiral Macrocyclic Ligands
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Cu~(2+)的柠檬酸配合物与大环配体交换反应的研究
A Study of Ligand Exchange Reaction between Cu ~ ( 2 + ) - Complexes and Macrocyclic Compound
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双大环配体与铜双核配合物的合成、晶体结构和磁偶合性质
Synthesis , Crystal Structure and Magnetic Properties of A New Dicopper ( II ) Complex with a Bis ( macrocyclic ) Ligand
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晶体结构显示:配合物1和2的金属离子与大环配体的4个氮原子及大环平面轴向的2个氯离子以八面体配位方式配位;
Each metal ion in 1 and 2 is six-coordinated with four macrocyclic nitrogen atoms in the equatorial plane and two chloride anions in axial positions .
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结果表明:配合物中的金属均是五配位并采用扭曲的四方锥构型,但由于轴向上的配位原子以及大环配体的不同它们的堆积结构有较大差别。
The results show that : All metal ions have five coordinated atoms with distorted square-pyramidal configuration . The crystal packings of complexes are different because of their different axial donor atoms and macrocyclic ligands .
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大环中性配体用作大块液膜载体分离金属离子的研究
A study of the separations of metal ion through bulk liquid membranes by macrocyclic carriers
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为探明不同金属离子在酯水解过程中的作用,本论文合成了一种十四圆大环Schiff碱配体。
In order to elucidate the effects of different metal ions on hydrolysis of esters , a 14-membered tetra-aza-macrocyclic Schiff base ligand and its Cu ( II ), Zn ( II ) and Co ( II ) complexes have been synthesized .
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含大环多胺配体金属磷酸酯水解酶模型化合物的合成、表征及催化性能研究
Synthesis , Characterization and Catalytic Activity Studies of Phosphoester Model Complexes Containing Macrocyclic Polyamine
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大环多胺及其金属配合物的研究新进展新型手性脂质性酰胺型大环多胺配体的合成
Recent Advances in Macrocyclic Polyamines and Their Metal Complexes SYNTHESIS OF NEW CHIRAL LIPOPHILIC MACROCYCLIC OXO POLYAMINES