配位键

IR分析表明：PVAc-Cu（Ⅱ）配合物中PVAc链节中的CH3COO&中的羰基氧提供孤对电子与金属离子Cu（Ⅱ）形成配位键。

The IR analysis shows that the oxygen in carbonyl group of CH_ ( 3 ) COO in PVAc chain unit provides lone pair electron to form the coordinate bond with metal copper ion Cu ( II ) .

红外光谱表明，稀土与TTA形成配位键，且稀土的掺入未改变Eu（TTA）3的结构。

IR analysis indicate that the coordinate bond between rare earth and TTA was formed , and the structure of Eu ( TTA ) 3was not destroyed when the rare earth was doped into Eu ( TTA ) 3 .

用X射线光电子谱（XPS）法研究粘接配位键机理

Study on the Mechanism of the Adhesin Co-ordinate Bond by X-ray Photoelectron Spectroscopy

在四面体构型中，中心B原子与吡啶环上的N原子形成了配位键，且配位键的键长在B原子与临近配体所形成的键长中最长。

In the typical tetrahedral geometry , the coordination bond length formed from between B and N on the pyridyl is the most longest .

结果表明：界面处元素N、O、Fe、Al发生了化学位移，从而证实了粘接界面配位键的存在。

The results show that the dis - placement thus the adhesion co-ate ordinate bond existing on the interface was proved .

研究表明配位键的强度不仅受取代基R的影响，而且还与环结构的变化有关。

The strength of the dative bond deponds not only on the substituents R , but also on the skeletal structure of the parent ring .

此外，异丙基钛酸酯与乙醇胺的反应物，证明分子内有N→Ti配位键生成。

In addition , The intra-molecular N → Ti coordinate linkage has also been identified in the reaction products of isopropyl titanate and ethyl hydroxyl amines .

锕系配合物中vanderwaals能与配位键能之间的平衡Ⅰ。

Balance between Coordination Bond and Van der Waals Energies of the Complex Compounds of Actinides I.

含分子内配位键的（MeOCH2CH2C5H4）2UCl2的合成及表征

Synthesis and Characterization of ( MeOCH_2CH_2C_5H_4 ) _2UCl_2 with Intramolecular Coordination Bond

XPS数据说明，－PPhZ基团中的磷原于与过渡金属钮之间形成配位键，满足一定空间结构的氧和氮原子也参与配位键的形成。

XPS data revealed that the coordination bonds were formed among phosphorous , some oxygen and nitrogen which meet steric structure and palladium atoms in the palladium complexes .

通过壳聚糖上的&NH2与Cu2+生成不饱合络合物，以高分子配位键法，对多酚氧化酶（PPO）固定化，实验结果表明这种方法是可行的。

A method for immobilization of polyphenol oxidases ( PPO ) was introduced . The PPO was immobilized on the coordinated polymer chitosan Cu 2 + .

配位键合Re（OPr~i）（TTA）2的发光有机玻璃的制备

Synthesis of Photoluminescent Organic Glass Containing Re ( OPr ~ I ) ( TTA ) _2 by Coordination Linkage

以荧光光谱和1HNMR谱研究了驱动四苯基卟啉锌（Ⅱ）[Zn（TPP）]咪唑基尾式卟啉铁（Ⅲ）[Fe（pImEPTPP）Cl]超分子自组装的配位键。

Coordination bonding driving supramolecular self-assembly of Zn ( TPP ) with Fe ( p - ImEPTPP ) Cl was investigated by fluorescence spectra and ~ 1H NMR .

结果表明，三异丙氧钇中Y（Ⅲ）与PUF中酚羟基上的氧形成了配位键；

The results showed that the coordination bonds were formed between Y (ⅲ) ions and phenolic hydroxyl group of PUF .

这是由于2Na-EDTA与金属离子结合，配位键联接的Gemini型表面活性剂浓度大幅度下降。

This is because 2Na-EDTA has great binding ability with metal ion and leads to the collapse of Gemini-type surfactant .

Mo-S簇合物与松散配位键的研究

Research on Mo-S clusters and the loose ligand bond

IR和PVAc-Fe（Ⅲ）配合物的XPS测试结果表明，PVAc的CH3COO中羰基氧提供孤对电子与金属离子形成配位键。

IR spectra and XPS showed the complex PVAc-Fe ( ⅲ ) is formed by non-paired electrons from oxygen atom of CH_3COO group in PVAc with metal ions .

复合微粒在溶液中的分散性明显优于TiO2；制备过程中TiO2的晶型没有发生改变；红外光谱分析表明TiO2和聚苯胺之间可能存在配位键和氢键等相互作用。

The dispersion of composite particles was better than TiO2 particles . TiO2 crystal type did not change in the prepared process . Infrared spectrum ( IR ) showed that intensive interaction ( hydrogen bond and coordinate bond ) existed between TiO2 particles and polyaniline .

γ-APS处理将铝板表面转变为氨基-NH2，PP-g-MAH的酸酐及其水解形成的羧基与-NH2在界面形成了配位键。

The pretreatment of γ - APS transforms the surface of aluminum sheet into amino group-NH_2.The covalent bond between carboxyl groups , - COOH on PP-g-MAH and amino group-NH_2 are formed at the interface .

通过LBA-603（配位键合剂）与HMX分子的-NO2基团的诱导效应，LBA-603可以在HMX表面形成一层粘附层，达到对HMX的包覆作用。

HMX is coated by LBA-603 ( ligand bonding agent ) which forms an adhesion level on the surface of HMX through the induction effect between LBA-603 and the – NO2 groups of HMX .

以Cu2+为模板离子，以环氧氯丙烷为交联剂，通过配位键作用，对化学键合在硅胶表面的PEI大分子链进行了离子印迹，制备了复合型Cu2+印迹材料IIP-PEI/SiO2；

Then the molecular imprinted polyethyleneimine on the surface of silica gel was prepared using Cu ~ 2 + as template ions and epichlorohydrin ( ECH ) as crosslinking agent via coordination bond effects , and composite ionic imprinted material IIP-PEI / SiO_2 was obtained .

聚乙二醇与Fe3O4形成配位键，提供位阻斥力改变Zeta电位和电荷面密度，对Fe3O4的粒径和分散性能无明显影响。

In a solution containing polyethylene glycol , the change of Zeta potential and surface charge is considered to be brought about by complex bond and position obstruction repulsion , which has no obvious effect on the diameter and dispersing property of Fe_3O_4 .

KQ1缓蚀阻焦剂与铁结合形成配位键，在金属表面形成一层吸附层，起到缓蚀阻焦的作用。

The KQ1 corrosion and coking inhibitor can combine with Fe into complex bond to form a adsorption layer on the surface of metal , it played a anticorrosion and anticoking part .

粘接配位键机理的实验研究（一）

Experimental Study on the Theory of the Adhesive Co-ordinate Bond (ⅰ)

这就是配位键长的综合模型。

This is the unified model of the coordination bond length .

表面增强拉曼光谱研究基于轴向配位键结合的金属卟啉自组装膜

SERS Spectroscopy Studies on the Self-assembled Films of Metalloporphyrin Based Axial Ligation

复合材料的两相界面为氢键键合和配位键合；

There are hydrogen bonding and ligand bonding between HA and PA ;

红外光谱表明，三氯化钌和邻菲啰啉形成配位键，且结构并没有被破坏。

The infrared spectrum showed that the structure of phenanthroline were not destroyed .

有机磷卤素镍络合物配位键振动光谱计算

Calculation for the Vibrational Spectra of Coordinate Bonds on Some Organic Nickel Complexes

离子极化作用的配位键模型及其应用

Coordination bonding model of ionic polarization and its application