酰氯

在多肽固相合成中，分别采用酰氯法和活化酯法，研究了20种Fmoc-氨基酸与Wang树脂的连接反应。

The reaction of twenty kinds of Fmoc-AA-OH linked to Wang resin using methods of acyl chloride or active ester was studied in solid-phase peptide synthesis .

传统的肽类合成多采用液相化学合成，常用的包括碳二亚胺（DCC）法，混合酸酐法、酰氯法、叠氮物法等等，为多肽的合成提供了多种选择。

Peptides are traditionally synthesized in liquid phase , such methods are DCC , mixed anhydrides , acyl chloride and azide etc. , which provide more choices for peptides synthesis .

研究通过丹磺酰氯柱前衍生，用HPLC对纳豆发酵过程中的生物胺进行检测。

Biogenic amines during the fermentation of natto was detected by HPLC , using precolumn derivatization with DNS-Cl.

以液体石蜡为原料，采用自行研制的催化剂PB进行磺酰氯化，可以得到一种十分重要的加脂原料-烷基磺酰氯。

A newly developed catalyst PB was used in the catalytic sulfonyl - chlorination of paraffin .

用特戊酰氯对吲哚-3-丙酸上的N进行保护，然后用氯化亚砜和三氯化铝进行酰化反应关环。

The N of indole-3-propionic acid is protected by pivaloyl chloride , and then thionyl chloride and aluminum chloride for acylation cyclization . 2 .

丹酰氯柱前衍生人尿液多胺高效液相色谱（HPLC）快速测定

High-Performance Liquid Chromatography ( HPLC ) Rapid Determination of Polyamines in Human Urine Following Pre-column Derivatization with Dansyl Chloride

Pd（Ⅱ）/γ-Al2O3催化有机锡试剂和酰氯偶联反应的研究

Study on the Coupling Reation of Organotins and Acid Chlorides Catalyzed by Pd (ⅱ) / γ - Al2O3

氯化介质中PbS固体表面的氯络合-溶解行为第三组仅加完全培养基。正十六烷基磺酰氯的合成

Complexation and Dissolution at the Surface of Solid PbS in Chloride Medium

用SiO2负载壳聚糖（CS），再负载PdCl2，制得催化剂SiO2CSPdCl2。研究其对三丁基烃基锡与酰氯偶联反应的催化活性。

A silica-supported chitosan-palladium catalyst ( SiO_2-CS-PdCl_2 ) was prepared for coupling reaction of organotins with acyl chlorides .

丹酰氯SiO2纳米发光标记物的制备

Preparation of Novel DNS-Cl Fluorescent Silica Nanoparticles

采用氰尿酰氯的方法，使用各种分子量的聚乙二醇修饰SOD，进行了修饰率和修饰活性残余率的测定。

SOD was modified by a series of PEG with cyanuric chloride method and modification ratio and activity remaining ratio of SOD were measured .

以荧光素和苯甲酰氯为原料制备了荧光素二苯甲酰酯，并用X射线单晶衍射法测定了晶体和分子结构。

The title compound has been prepared from the reaction of fluorescein and benzoyl chloride . Its crystal and molecular structure is determined by single crystal X-ray diffraction .

活性炭吸附CS2解析气相色谱法测定车间空气中的O，O-二乙基硫代磷酰氯

Determination of O , O-diethyl Thiophosphoryl Chloride in the Air of Workplace by GC with Active Carbon for Adsorption and CS2 for Desorption

二乙醇胺和对甲苯磺酰氯在三乙胺存在下，反应生成N，0，O′－三（对甲苯磺酰基）双（2－羟乙基）胺，产率93%。

In the presence of triethylamine , N , O , O ' - tris ( p-toluenesulfonyl ) his ( 2-hydroxyethyl ) amine was prepared in 93 % yield by tosylation of diethanolamine with p-toluenesulfonyl chloride .

方法：采用氰脲酰氯法先对聚乙二醇-6000（PEG-6000）进行活化，再以活化后的聚乙二醇对牛血Cu，ZnSOD进行化学修饰，制得PEGSOD。

Methods : PEG SOD ( PEG-6000 ) was obtained after Cu , Zn SOD in bovine blood was modified by PEG-6000 activated with cyanuric chloride method .

微波辐射下NaBPh4的Suzuki偶联及端炔与酰氯的偶联反应研究

Study on the Suzuki coupling of NaBPh_4 and coupling reaction of terminal alkynes with aroyl chlorides under microwave irradiation

本论文以阿昔洛韦（Acyclovir，ACV）为原料与棕榈酰氯反应合成了阿昔洛韦棕榈酸酯（AcyclovirPalmitate，ACVP）。

Acyclovir palmitate ( ACVP ) was synthesized from acyclovir ( ACV ) and palmitoyl chloride .

通过脂肪酰氯与茶多酚（TP）的反应，制备出了一系列含不同直链脂肪基团的脂溶性茶多酚（LTP）。

Liposoluble tea polyphenols ( LTP ) with varying aliphatic groups were synthesized by reaction of aliphatic acyl chloride and tea polyphenol ( TP ) .

结果表明，中间体龙脑酰基二酯的最佳合成条件为：乙氧基镁丙二酸酯和D龙脑酰氯的物质的量配比为1∶14，反应时间为4h，反应温度为在乙醚溶液中回流；

Results show that the optimal esterifying conditions are the ratio of 1 ∶ 1.4 and the reaction time of 4 h under reflux .

苯甲酰氯和D酒石酸反应生成D2，3二苯甲酰酒石酸酐，后者于丙酮水溶液中水解得到拆分剂D2，3二苯甲酰酒石酸。

The resolving reagent , D-2,3-dibenzoyl tartaric acid was obtained by hydrolyzation of D-2,3-dibenzoyl tartaric anhydride prepared by reaction of benzoyl chloride with D-tartaric acid .

酰氯化反应条件为：草酰氯为酰氯化试剂，DMF为催化剂，收率90.7%。

The optimal parameters of acyl chlorination were selected as follows : oxalyl chloride as acyl chloride reagent , DMF as catalyst , the yield was 90.7 % .

方法：在合成乙酰水杨酰氯时以DMF为催化剂，然后用聚乙二醇（PEG）为相转移催化剂酯化而得贝诺酯。

Method : When Acetylsalicylryl chloride was synthesized , DMF as catalysis was added , and Benorilate was obtained in the presence of Polyethylene glycol ( PEG ) phase transfer catalyst .

以月桂酰氯、棕榈酰氯为酰化剂合成N－长链酰基谷氨酸，研究了合成反应机理和工艺参数，确立了较适宜的产品制造工艺，放大试验结果为收率96%－98%。

A series of N-long chain acyl glutamic acids were synthesized from acylating agents , such as lauroyl and palmitoyl chloride . The reaction mechanism , as well as the technology parmeters were studies so that an experiments reached 96 % - 98 % k.

由氨基酸组成求得最小分子量约16500。（4）用二硝基氟苯，二甲基氨基萘磺酰氯及氨肽酶M测定抑制剂A、B的N末端，都证实是天冬氨酸。

The minimum molecular weights as estimated from the amino acid compositions were about 16,500 . For both inhibitors A and B the N-terminal amino acid was aspartic acid , as determined by the FDNB and DNS-Gl methods and further confirmed by enzymic hydrolysis with aminopeptidase M.

四丁基溴化铵（TBAB）为相转移催化剂、环己烷为溶剂，用己内酰胺和苯甲酰氯合成了N-苯甲酰基己内酰胺。

Using TBAB as phase transfer catalyst , N benzoyl caprolactam was synthesized from benzoyl chloride and caprolactam in cyclohexane .

本文主要以甲烷磺酸做溶剂，以己酰氯为酰化试剂，合成不同取代度（DS）的已酰化壳聚糖（HC）。

In this work , hexanoyl chitosan ( HC ) with different degree of substitution ( DS ) were synthesized by acetylation reaction using MeSO_3H as a solvent and capronyl chloride as acylated reagent .

采用低温溶液法共缩聚反应合成了对苯二甲酰氯（TPC）摩尔分数为0.05~0.15的改性间位芳香族聚酰胺（PMIA）共聚物。

Modified meta-aramid ( PMIA ) copolymer with TPC mole fraction of 0.05 ~ 0.15 was prepared by low-temperature-solution polycondensation in DMAc .

化合物2再在三乙胺作用下与2mol的甲烷磺酰氯反应制成甲磺酸酯（3）；

The compound 2 then reacted with 2 equiv. of methylsulfonyl chloride and 3 equiv.

第一步将肉桂酸制成肉桂酰氯，第二步将肉桂酰氯与苄醇反应制得肉桂酸苄酯。结构经IR，1HNMR和MS确证。

Benzyl cinnamate was synthesized by a two-step reaction : cinnamic acid reacted with thionyl chloride giving cinnamyl chloride and cinnamyl chloride was then reacted with benzyl alcohol giving benzyl cinnamate whose structure was characterized by IR , 1H NMR and MS.

本文用红外光谱仪（FTIR）、紫外分光光度计（UV）对在无水AlCl3存在下萘与草酰氯反应合成的1,1′和1,2′二萘甲酮的结构进行了研究。

The structure of 1 , 1 ′ - and 1 , 2 ′ - dinaphthyl methanone synthesized by the reaction of naphthalene with oxalyl chloride in the presence of AlCl 3 were studied by using UV and FTIR in this paper .