活性自由基聚合

具有RAFT链转移过程的活性自由基聚合的MonteCarlo模拟

Monte Carlo Simulation on Living Radical Polymerization with RAFT Process

St和MMA在不同反应介质中的RAFT活性自由基聚合

RAFT Living Free Radical Polymerization of St and MMA in Different Reaction Media

RAFT调控的活性自由基聚合动力学研究及其在合成复杂结构聚合物上的应用

Kinetics of RAFT Based Living Free Radical Polymerization and Application in Synthesis of Complex Architecture Polymer

增溶剂存在下苯乙烯细乳液RAFT活性自由基聚合

Reversible Addition-Fragmentation Transfer ( RAFT ) Living Polymerization of Styrene Miniemulsion in the Presence of Solubilizer

基于活性自由基聚合的纳米SiO2表面接枝及其应用

Grafting Polymers from the Surface of Silica Nanoparticles via Living Radical Polymerization and Their Applications

增溶剂存在下甲基丙烯酸甲酯乳液和细乳液RAFT活性自由基聚合

Emulsion and Miniemulsion Polymerization of MMA Via Reversible Addition-Fragmentation Transfer ( RAFT ) in the Presence of Solubilizer

可逆加成-断链链转移（RAFT）聚合是活性自由基聚合方法之一，它结合了活性聚合和自由基聚合的优点。

Reversible Addition-Fragmentation chain Transfer polymerization is one of the living radical polymerizations . It combines the advantage of living polymerization and radical polymerization .

利用合成的二硫代苯甲酸苯乙基酯为链转移剂，成功实现了MMA和St在本体及甲苯中的RAFT活性自由基聚合，结果表明均有较为明显的活性聚合特征。

The rarefied was used as transfer agent for the RAFT polymerization of MMA and St in bulk and toluene , the polymerizations were found with living characters .

原子转移自由基聚合（ATRP）方法是一种新发展起来的可控/活性自由基聚合方法，在合成结构可控共聚物过程中具有广泛应用。

Atom transfer radical polymerization ( ATRP ) is a new effective method to prepare controlled block copolymers .

以二硫代羧酸酯和三硫代碳酸酯为链转移剂的可逆加成裂解链转移（RAFT）自由基聚合的发现，在活性自由基聚合领域是一个重要突破。

RAFT uses the dithiocarbamate or trithiocarbonate derivatives as transfer agents , the polymerization has excellent living behavior , which is an important breakthrough in the development of living free-radical polymerization .

结果表明，该聚合体系呈现活性自由基聚合的特征，即聚合物分子量随单体转化率呈线性增长，分子量分布较窄，ln（[M]0/[M]）和聚合时间之间存在线性关系。

The results show that the molecular weight increases linearly with the increase of the monomer conversion , the molecular weight distribution ( MWD ) is narrow and a linear relationship between ln ( [ M ] 0 / [ M ] ) and polymerization time exists .

此外，以可控／活性自由基聚合中的应用研究为理论背景，将MonteCarlo方法应用于反应型受阻胺哌啶衍生物（r-HAPD）的光聚合动力学的计算机模拟，考察了r-HAPD光聚合的活性动力学特征。

The author used a Monte Carlo simulation algorithm to investigate the reaction kinetics and molecular weight distribution of free-radical photopolymerization of r-HAPD , which was consistent with the characteristic of Living free-radical photopolymerization or not .

结合阴离子聚合和活性自由基聚合方法合成了聚环氧乙烷-聚丙烯腈两亲性嵌段聚合物（PEO-b-PAN）。

Amphiphilic block copolymer poly ( ethylene oxide ) - polyacrylonitrile ( PEO-b-PAN ) have been synthesized through the combination of anionic polymerization and atom transfer radical polymerization ( ATRP ) .

水介质中可控活性自由基聚合的研究进展

The Development of Controlled / living Radical Polymerization in Aqueous Media

富马酸亚铁催化甲基丙烯酸甲酯活性自由基聚合的研究

Atom transfer radical polymerization of Methyl Methacrylate Catalyzed by ferrous fumarate

红外光谱原位跟踪活性自由基聚合反应过程研究

Study of " Living " Radical Polymerization by FTIR in Situ

活性自由基聚合的新进展&原子转移自由基聚合

The Latest Development of Living Radical Polymerization & Atom Transfer Radical Polymerization

硫代苯甲酸存在下辐射引发活性自由基聚合

Living radical polymerization induced by radiation in the presence of dithiobenzoic acid

活性自由基聚合研究的新动态&可逆加成-断裂链转移自由基聚合

New trend of living radical polymerization Reversible addition-fragmentation chain transfer radical polymerization

可控/活性自由基聚合及其应用研究

The Study of Controlled / Living Free Radical Polymerization and Its Application

活性自由基聚合在高分子合成中的应用

Applications of Living Free Radical Polymerization in Macromolecular Synthesis

2,2′-联吡啶与丙二腈对苯乙烯活性自由基聚合的影响

2,2 ′ - Bipyridine and Malononitrile as Additives for Styrene Living Radical Polymerization

探讨了这种活性自由基聚合反应机理。

This living radical photopolymerization mechanism was explained .

活性自由基聚合反应合成超支化聚苯乙烯及其性能研究

Studies on the preparation and properties of hyper - branched polystyrene from living radical polymerization

活性自由基聚合经过十多年的发展，已成为一种有效的高分子设计手段。

Inhibition and retardation effects of N , N-diethylhdroxyamine on free radical polymerization of styrene ;

应用活性自由基聚合制备有机/无机杂化材料及其性能表征

Preparation and Properties of Organic / Inorganic Hybrid Materials via " Living " Controlling Polymerization

卤素存在下的活性自由基聚合

Living Radical Polymerization with Halogen Existent

活性自由基聚合方法合成端羟基聚乙烯基吡咯烷酮-苯乙烯共聚物

Synthesis of Hydroxyl-Terminated Poly ( 4-Vinyl Pyrrolidone ) and its Copolymer by Living Free Radical Polymerization

实验结果说明，聚合反应过程服从活性自由基聚合的规律。

The experimental results show that the polymerization possesses living / controlled natures of free radical polymerization .

Cr~（2+）+BPO体系引发的活性自由基聚合

Living Radical Polymerization Initiated by the Aged Cr ~ ( 2 + ) + BPO Complex System