不良溶剂
- 网络poor solvent;non-solvent;bad solvent
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特别对于不良溶剂情况,在高接枝度时大多数反离子聚集在界面附近。
Especially in the poor solvent case , most of counterions gather near the interface at high grafting densities .
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微球收率随架桥剂用量减少,良溶剂用量增加而增加;并且受到不良溶剂中乳化剂种类的影响。
The recovery of the microspheres is increased with decreasing the bridging liquid and increasing the good solvent and poor solvent .
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我们的结论是对聚合物来说,越是不良溶剂,则GPC普适标定的适用性越小。
Our conclusion is that the poorer the solvent for the polymer , the smaller the suitability of the GPC universal calibration .
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AS溶解在相对不良溶剂,其在TATB表面上的被吸附量大于相对良溶剂中的。
AS can be more easily adsorbed at the surface of TATB in non-solvent than in good solvents .
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与单体/聚合物不溶体系的悬浮态乳液聚合相比,对于MMA悬浮态乳液聚合,需要加入聚合物的不良溶剂,如环己烷,才能得到疏松、多孔结构的聚甲基丙烯酸甲酯(PMMA)树脂。
Comparing with the suspended emulsion polymerization of monomer / polymer dissoluble system ( such as vinyl chloride ), non-solvent of PMMA , such as cyclohexane , must be added to the polymerization system , to obtain porous PMMA resin .
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在甲苯-C60体系中通过缓慢滴加不良溶剂的方法制备了具有树枝状和花簇状的C60纳微米结构。8.本课题组首次用富勒烯C60/C70混合物制备出C60/C70纳米纤维。
The flower cluster and dendritic-like structure of C60 micro / nanometer structures was prepared by slowly dropping in toluene-C60 system . ( 8 ) The C60 / C70 nanofibers were synthesized with a mixture of fullerenes C60 / C70 powders .
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歌剧中的穷途末路Florg-Huggins法不宜用于聚合物与不良溶剂形成的体系。
The Flory-Huggins method is unsuitable to those polymer solutions which consist of polymer and poor solvents .
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而对其不良溶剂如正己烷、甲苯几乎不响应。
But the response of the resistors to the poor solvent of PEG such as n-hexane and toluene , is hardly observed .
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而经不良溶剂处理后,接枝链卷曲成团,形成孤立的球状结构。
In good solvent , grafted chains stretched to form flake structure , while in poor solvent they curled to form round configuration .
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由无定形聚苯乙烯不良溶剂(如庚烷、异辛烷等)配制的悬浮液,固含量小于15%时,体系呈现牛顿流体性质。
However , when the suspension is prepared by a non-solvent for amorphous polystyrene , such as heptane and isooctane , and the sPS content is lower than 15 % , the fluid is Newtonian .