汞电极
- mercury electrode
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研究了亚硝基R盐在汞电极上的电化学行为和电极反应机理。
The electrochemical behavior of Nitroso R salt on mercury electrode was investigated , and the mechanism of the reaction was discussed .
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汞电极电位法测定EDTA螯合物的稳定常数
Mercury electrode method for the determination of stability constants of EDTA chelates
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悬汞电极伏安法测定药物中维生素B1的含量
Determination of VB_1 in the Medicine by Hanging Mercury Drop Electrode Voltammetry
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铜锌超氧化物歧化酶(Cu2Zn2SOD)在汞电极上的吸附研究
A Study on Adsorption of Copper-Zinc Superoxide Dismutase ( Cu_2Zn_2SOD ) on Mercury Electrodes
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Ni(Ⅱ)离子在悬汞电极上阴极还原的计时电位法研究
A chronopotentiometric study of the cathodic reduction of nickel (ⅱ) ion at a hanging mercury drop electrode
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新型镀锌添加剂SD-1在悬汞电极上吸附行为的研究
Study of adsorption behaviors of a new type additive SD-1 for plating zinc on hanging mercury electrode
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防吸附物理涂汞电极示差反向极谱法测定海生物中痕量Zn、Cd、Pb及Cu
The analysis of zn , cd , pb , Cu in marine organisms by anti adsorption physical coating mercury electrode inverse polarography
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汞电极法研究络合物的稳定性Ⅰ.二价金属的EDTA络合物
Mercury electrode in the study of complexes ⅰ . stability constants of EDTA chelates of bivalent metals
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吡哌酸在该溶液中的汞电极上的吸附服从Langmuir等温线,吸附系数β=5.4×105;
The adsorption of PPA on the surface of mercury electrode complied with Langmuir isotherm .
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在弱酸性的EDTA介质中,铌(Ⅴ)在滴汞电极上还原时,出现两个极谱波。当有氯酸钾存在时,则产生催化电流;
When niobium (ⅴ) and chlorate are present in weak acidic EDTA medium , a catalytic wave is produced .
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第二、三章分别使用玻碳电极和滴汞电极研究了孔雀石绿与DNA的相互作用。
In the second and the third parts , the interactions of malachite green with DNA have been investigated by carbon glassy electrode ( GCE ) and drop mercury electrode ( DME ), respectively .
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本文采用恒电位方波法,测绘了在NaOH溶液中,不同浓度的DE、DPE&Ⅲ及其混合物在滴汞电极上的微分电容曲线。
By potentiostatic square wave methods , the differential capacity curves of different concentrations of DE . DPE & ⅲ and their mixture in NaoH solutions on dropping mercury electrode were serveyed and drew .
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NH3/NH4Cl中钴(Ⅱ)-丁二肟体系在悬汞电极上电化学还原机理的研究
A Study on Mechanism of the Electrochemical Reduction of Co (ⅱ) - Dimethylglyoxime System at Hanging Mercury Drop Electrode in NH_3 / NH_4Cl
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在氢氧化钠溶液中TeO3~(2-)在悬汞电极上的电化学行为
The Electrochemical Behaviour of TeO_3 ~ ( 2 - ) on Hanging Mercury Drop Electrode in Sodium Hydroxide Solution
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本文研究了用J型汞电极的电位滴定法测定金属离子副反应系数αM的方法及原理,测定了Zn~(2+)与醋酸根、柠檬酸根、草酸根等的副反应系数。
The method and principle of determining side-reaction coefficient α _M of metal ion were studied with mercury electrod . Side-reaction coefficients of Zn ~ ( 2 + ) with acetate , citrate and oxalate were determined .
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溶出峰具有吸附性质,在悬汞电极上的吸附符合Frumkin等温式。
The experiment showed that the peak had adsorptive property and obeyed Frumkin isotherm .
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在汞电极表面,喹乙醇的吸附遵从Frumkin吸附等温式。
On the surface of mercury electrode , the adsorption of olaquindox obeys Frumkin isotherm .
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氯盐溶液中的Zn(Ⅱ)离子在汞电极上阴极还原的两电荷传递一步完成,电极过程表现为扩散传质步骤控制的可逆电极过程动力学规律。
It is a reversible electrode process that the cathodic reduction of zinc (ⅱ) ion occurs at the mercury electrode in an chloride solution . In the electrode process the transfer of two charges occurs in one step and the diffus-ion is a rate-determining step .
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本文讨论了钒(V)与5-Br-PADAP形成的配合物在悬汞电极上的不可逆吸附还原的导数吸附伏安法,并用所建立的方法测定了自来水中超痕量的钒(V)。
Derivative technique is applied to irreversible reduction of the vanadium complex with 5-Br-PADAP at a hanging mercury drop electrode using linear sweep adsorption voltammetry . The theoretical and analytical characteristics have been investigated with first and second order derivative technique .
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荧光镓在汞电极上的吸附符合Frumkin等温式。
At pH 4 and at the surface of mercury electrode , the adsorption of LMG obeys Frumkin isotherm .
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几种ASV仪器已成功的用于铅检测,但它们中的大多数工作电极都使用滴汞电极,或汞膜电极。
Several techniques of ASV have been successfully employed for lead detection , but most of them involved either hanging mercury drop electrodes , or mercury film electrodes .
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SH-84型精密挤压式悬汞电极的研制
Development of model SH-84 hanging mercury drop electrode
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而当其浓度约高于80ppb时,其还原波还叠加了Te(0)与结晶紫在汞电极表面上生成的电活性配合物之吸附波。
When the concentration is higher an adsorption wave may have been superimposed on the hydrogen catalytic wave . The adsorption wave is produced from an electro-active complex of crystal violet with Te ( 0 ) formed . on the surface of DME .
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本文详细地研究了铜的腺嘌呤(Ade)络合物在悬汞电极(HMDE)表面上的吸附形态和伏安行为。
The adsorptive species and voltammetric behaviour of copper complexes with adenine ( Ade ) at the surface of hanging mercury drop electrode have been studied in detail .
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研究结果表明,5-Fu可与汞电极阳极极化,产生的Hg(Ⅱ)在电极表面生成难溶化合物Hg-5-Fu,该化合物具有链状大分子结构。
It is shown that 5-Fu can combine with Hg (ⅱ) generated by anodic polarization forming an insoluble complex on electrode surface , The Hg-5-Fu complex is deemed to be a macromolecule with chain structure .
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此外,对BDMN及二氧六环在汞电极上的吸附现象也进行了研究。
The adsorption of BDMN and solvent ( dioxane ) on the dropping mercury electrode has also been studied .
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测得在悬汞电极上的饱和吸附量为1.03×10-9mol·cm-2。该方法用于PbS2O3溶度积的测定,结果与文献值基本一致。
The saturated adsorptive amounts of S 2O 3 2 - was measured to be 1.03 × 10 - 9 mol / cm2 . The method was applied to determine the solubility products ( K sp ) of PbS 2O 3 with satisfactory results .
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在HCl-NaAc底液中,铅(Ⅱ)与碘(Ⅰ)可生成稳定络合物,并且能在滴汞电极表面被吸附,产生灵敏的络合吸附波,示波极谱的峰电位(vs.SCE)为-0.55V。
In HCl-NaAc buffer solution , Pb ~ ( 2 + ) with I ~ - can form stable compounds adsorbed on the surface of a mercury dropping electrode and produce a sensitive polarographic wave with peak potential at ( 0.55 V ) ( vs. SCE ) .
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在汞电极上电还原糖得到相应多元醇的研究
Electroreduction Sugars to Polyalcohols from Alkaline Aqueous Media on Mercury Electrodes
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物理涂汞电极稳定性研究
A study on the stability of physically coated mercury film electrode