茂金属催化剂

SBS加氢茂金属催化剂开发动向

New developing trends of metallocene catalysts for SBS hydrogenation

概述了国外SBS、SIS等聚合物加氢茂金属催化剂的研究开发进展；

The article resumes world 's research advance on metallocene catalysts for SBS hydrogenation ;

负载型非茂金属催化剂聚合制备UHMWPE

Preparation of UHMWPE by Supported Non-metallocene Catalysts

茂金属催化剂在LLDPE装置上的应用

Application of metallocene catalyst in LLDPE plant

详细叙述了采用茂金属催化剂生产的聚烯烃，如聚乙烯（PE）、聚丙烯（PP）的性能及应用情况。

The article also examines the applications and performance of some olefin polymers produced using metallocene catalysts , such as polyethylene ( PE ) and polypropylene ( PP ) .

RESS共沉析制备负载型茂金属催化剂（Cp2TiCl2/PMMA）微粒

Study on Producing Microparticles of Supported Metallocene Catalyst ( Cp_2TiCl_2 / PMMA ) by Co-Precipitation of RESS

概述了采用茂金属催化剂生产的sPS（间规聚苯乙烯）的各种优异性能及其应用领域，并作了市场预测。

The excellent properties and applications of sPS by metallocene catalyst were introduced , and the market of sPS were analyzed .

由于茂金属催化剂价格昂贵，国内生产的聚丙烯多为Ziegler-Natta等规聚丙烯。

The metallocene catalyst is expensive , so most polypropylene in domestic industry is prepared by Ziegler-Natta catalyst .

烯烃聚合催化剂主要包括Ziegler-Natta催化剂、茂金属催化剂和茂后过渡金属催化剂。

The field of olefin polymerization catalysis has experienced Ziegler-Natta catalysts , metallocene catalysts and post-metallocene catalysts periods .

以复合茂金属催化剂和双载体茂金属催化剂催化乙烯聚合、考察聚乙烯（PE）分子量分布变化情况。

The composite metallocene catalyst and metallocene catalyst supported on mixed carrier was employed for ethylene polymerization , respectively . The variation in molecular weight distribution ( MWD ) of polyethylene ( PE ) was studied .

概述了茂金属催化剂和单活性中心技术的发展，介绍了聚乙烯（PE）生产技术新的发展动向，如双峰PE生产技术、反应器新配置技术、冷凝态和超冷凝态技术。

This paper summarized the development of metallocene catalyst and single-site center technology , and introduced the developing trends of polyethylene producing processes including bimodal PE production technology , responser new disposition technology and condensed and super-condensed technology .

用茂金属催化剂制得间规聚苯乙烯（sPS）是一类新型结晶聚合物，具有优良的耐热性、耐化学性和电气性能。

Syndiotactic polystyrene ( sPS ) produced with metallocene catalyst is a novel crystalline polymer that possesses excellent electronic / electric properties and good abilities to resist heat and chemicals .

利用苯并氮杂卓镍催化剂和茂金属催化剂的复配，实现了对乙烯的原位聚合改性，制备了线性低密度聚乙烯（LLDPE）。

In the second part , combination of metallocene metal catalyst and late transition metal complexes were used to in situ polymerize ethylene to prepare LLDPE using MAO as co-catalyst .

非茂金属催化剂中，FI催化剂较为突出，其催化烯烃聚合活性高，且能得到高分子量、窄分子量分布的聚乙烯和烯烃嵌段共聚物。

FI catalyst is prominent among post-metallocene catalysts . It can obtain polyethylene and block copolymers with high molecular weight and narrow molecular weigh distribution in a very high activity .

采用过氧化物交联，讨论了交联剂、共交联剂、补强填充剂以及增塑剂等对采用茂金属催化剂合成的乙烯－辛烯共聚物（POE）的物理机械性能的影响。

The influences of crosslinking agent , co-crosslinking agent , reinforcer and plasticizer on the mechanical properties of polyolefin elastomers ( POE ) were discussed with peroxide as crosslinking agent using metallocene catalyst .

为中山大学高分子研究所烯烃配位聚合研究室在高效Ziegler-Natta催化剂、茂金属催化剂烯烃聚合与共聚合方面部分研究工作的概述。

Polymerization and Copolymerization of Olefins with High Active Catalysts Researches on polymerization and copolymerization of olefins with Ziegler-Natta catalyst and metallocene catalyst from our laboratory are summarized in this paper .

负载茂金属催化剂的聚丙烯颗粒制备的反应器合金与传统Z-N催化剂合成的反应器合金相比，其共聚物的链结构更加无规。

Ethylene-propylene copolymers in reactor alloys obtained from metallocene supported PP particles showed much more random features than that prepared with conventional Z-N catalyst .

研究了加工温度、辛烯含量和炭黑填充量对用茂金属催化剂合成的聚烯烃弹性体（POEs）流变性能的影响。

Influences of the temperature , octene content and carbon black reinforcer on rheology behavior of polyolefin elastomers ( POEs ) produced using metallocene catalyst were investigated .

介绍了国内外聚丁烯-1技术现状，包括聚丁烯-1的Z-N催化剂和茂金属催化剂研究进展，以及聚丁烯-1生产工艺技术，并简要说明了我国聚丁烯-1树脂具有很大的开发潜力。

The developing of Ziegler-Natta catalyst and metallocene catalyst and producing technical aspect at home and abroad and the production technology of polybutene-1 are summarized in this paper .

用均相茂金属催化剂（n-Bu）Cp2ZrCl2/MAO对1-癸烯的齐聚合进行了研究。

The synthesis of oligomer from 1-decene with metallocene catalyst ( n-Bu ) Cp2ZrCl2 / MAO was studied .

在不同搅拌型式的聚合反应器中使用均相茂金属催化剂（CpTi（OR）3/MAO/TIBA）催化苯乙烯本体间规聚合。

The bulk syndiotactic polymerization of styrene catalyzed by homogeneous metallocene catalyst ( CpTi ( OR ) 3 / MAO / TIBA ) was carried out in various reactors with different agitators .

新型茂金属催化剂和载体型Z-N催化剂的合成、表征及催化烯烃聚合反应研究氯化镁/二氧化硅复合载体型Z-N催化剂的乙烯聚合性能

Studies on Synthesis , Characterization and Catalysis for Olefin Polymerization of Novel Metallocene Catalysts and Ziegler-Natta Catalysts ; PERFORMANCE OF ZIEGLER-NATTA CATALYST ON MgCl_2 / SiO_2 COMPOSITE SUPPORT FOR ETHYLENE POLYMERIZATION

简要叙述了传统Ziegler-Natta催化剂的发展，介绍了茂金属催化剂的结构类型和性能特点，并对新一代后过渡金属烯烃聚合催化剂的研究进展作了述评。

Briefly presents the development of the conventional Ziegler-Natta catalysts , presents the structure types and property features of metallocene catalysts , and comments on the development advances on new generation late transition metal catalysts used in ethylene polymerization .

综述了Ziegler-Natta聚丙烯催化剂技术的发展历史与研究动态，介绍了茂金属催化剂和后过渡金属催化剂的研究进展，展望了未来聚丙烯催化剂技术的发展前景，提出了我国发展聚丙烯催化剂的建议。

The development history and research trends of Ziegler - Natta polypropylene catalyst technologies are summarized ; the research development of metallocene and late transition metal catalysts are introduced ; the future foreground of polypropylene catalyst technologies are prospected ;

并通过对比详述了茂金属催化剂和Ziegler-Natta（Z-N）催化剂的催化机理，以及这两类催化剂对聚合物分子量和性能的影响。概括了对聚合物分子量影响的几种因素。

With comparison between the mechanism of these two kinds of catalysts of metallocene catalyst and Natta Ziegler ( Z-N ) of catalyst and details on the effects of polymer molecular weight polymer molecular weight , summarized the several influential factors .

茂金属催化剂具有能控制聚合物的分子量、分子量分布和立体规整度等突出优点，已成为继zigler-Natta催化剂之后的一类性能优异的烯烃聚合催化剂。

Metallocene catalysts , with the possibility of tailoring the polymer properties such as the molecular weight and the molecular weight distribution as well as stereochemistry , have become the excellent catalysts for the polymerization after the Zieger-Natta catalyst .

茂金属催化剂淤浆法聚乙烯中试聚合评价

Pilot Plant Evaluation of Metallocene Catalyst in a Slurry Polyethylene Process

新型桥联烯烃聚合茂金属催化剂研究进展

The Developement of Research on New-bridged Metallocenes in Catalytic Olefin Polymerization

核壳聚合物负载茂金属催化剂及乙烯聚合

Core-shell Polymer / Cp_2TiCl_2 Catalysts and their Behaviors in Ethylene Polymerization

茂金属催化剂样品的预处理对其金属元素测定的影响

Influence of sample preparation on determination of element in metallocene catalyst