金属卟啉

水溶性高分子金属卟啉络合物的合成及其与DNA作用的研究

Studies on the syntheses of water soluble polymeric metalloporphyrin complexes and their interaction with DNA

氰类和酯类取代基水溶金属卟啉与DNA相互作用的共振拉曼研究

The Interaction of Water-soluble Quaternary Ammonium Pyridine Porphyrins with DNA Studied by Resonance Raman Spectroscopy

CO2与环氧化合物聚合反应的金属卟啉催化体系研究

Progress in Copolymerization of Carbon Dioxide with Epoxides Catalyzed by Metalloporphyrin System

长链烷氧基取代金属卟啉／H2O2体系催化烯烃环氧化反应研究

Epoxidation of styrene with hydrogen peroxide catalyzed by long chain alkoxyl-substituted metalloporphyrins

负载化金属卟啉化合物催化剂结构的表征Ⅱ电子自旋共振和X射线光电子能谱

Study on the structure of supported metalloporphyrins ─ⅱ electron spin resonance and X-ray photoelectron energy spectrum

金属卟啉表面吸附NO的XPS和IR研究

Nitric Oxide Absorbed on Metalloporphyrin Complexes by XPS and FTIR Spectroscopy

四（3，5－二叔丁基－4－甲氧基苯基）金属卟啉的合成及NMR研究

Synthesis and NMR Study of Tetrakis ( 3,5-di-t-butyl - 4-methoxyphenyl ) metal Porphyrins

X射线衍射光谱分析显示，TPP和四苯基金属卟啉粉末均有较高的结晶度。

X-ray diffraction study showed that crystallinities of TPP and its metal coordination compounds were high .

金属卟啉Co（Ⅱ）[p-N（CH3）3]TPPI与CO加合性质的研究

Studies of the adductive property of metallic porphyrin co (ⅱ) [ p-n ( ch_3 ) _3 ] tppi with CO

实验表明，所合成的高分子金属卟啉络合物在同DNA作用时存在有嵌入模式，金属卟啉络合物大的平面环疏水结构和亲水性基团的引入促进了这种作用。

It indicates that the introduction of hydrophilic groups and the planar hydrophobic macrocyclic structure of metalloporphyrin complexes jointly increase the interaction of these polymeric metalloporphyrin complexes with DNA .

研究结果表明，金属卟啉的外围取代基苯基与卟啉环的键合能力按Mn、Fe和Co的次序变弱。

The experimental result indicated that the bonding power between substitutional phenyl and porphyrin cycle in metalloporphyrins became weak from Mn , Fe to Co.

担载金属卟啉模拟细胞色素P-450的催化丙烯环氧化

Propylene Epoxidation Catalyzed by a Biomimetic System of Cytochrome P450 Supported Metalloporphyrin on SiO_2

金属卟啉催化下环己烷羟基化反应中的Hammett关系

Hammett Relationship in Cyclohexane Hydroxylation Catalyzed by Metalloporphyrins

利用荧光探针技术和圆二色谱等分析手段对两种水溶性高分子金属卟啉络合物同DNA的作用进行了初步研究。

The modes and activities of the interaction of DNA and water soluble polymeric metalloporphyrin complexes , which have been prepared by polymeric analogous reaction and copolymerization , have been discussed according to circular dichroism spectra and fluorescent probe method .

用固载金属卟啉模拟细胞色素P-450单加氧酶体系，具有重要的学术价值和应用前景。

Modeling cytochrome P-450 monooxygenase with supported metalloporphyrins is very useful in research and application of them .

卟啉和金属卟啉化合物具有高的荧光量子产率、大的Stokes位移、相对长的激发和发射波长，而被广泛应用于分子识别中。

Porphyrin and porphyrin metal compounds with high fluorescence quantum yield , large Stokes shift , the relative length of the excitation and emission wavelengths , and is widely used in molecular recognition .

通过扫描电镜（SEM）分析模板剂&溴代十六烷基吡啶（CPBr）的加入对金属卟啉配位聚合物微观形貌的影响。

The effect of template & bromohexadecyl pyridine ( CPBr ) on the microcosmic structures of these coordination polymers have been analyzed by SEM .

目的探讨金属卟啉的光动力学作用对人膀胱癌细胞增殖和凋亡基因bcl-2、bax表达的影响及其诱导细胞凋亡的机制。

Objective To observe the effects of photodynamic therapy ( PDT ) of metalloporphyrin on proliferation and the expression of bcl-2 and bax genes which regulated cell apoptosis in human bladder cancer cells and to study its mechanism .

卟啉和金属卟啉的设计合成及其作为光敏化剂敏化TiO2的研究瑞士化学家认为，催化剂首先把敏化剂吸到它的表面并附着在那里。

Novel Substituted Porphyrins and Metalloporphyrins : Synthesis , Characterization and Photo-catalytic Activity of Their TiO_2-based Composites The Swiss chemists think that the catalyst first draws the sensitizer to its surface and holds it there .

将金属卟啉（MPs）仿生催化剂用于分子氧氧化烃类物质的氧化过程，这是当今催化剂化学与有机化学中极为重要的研究领域，尤其是非均相金属卟啉催化剂的催化氧化作用备受关注。

Metalloporphyrins biomimetic catalyst has been used to oxidate hydrocarbons with molecular oxygen ; this is one of the most important domains of catalysis chemistry and organic chemistry at present . Especially , the heterogeneous catalyst is being paid more attention to .

高密度可录光盘存储材料：金属卟啉配合物

High Density Recordable Optical Disk Storage Materials : Metal Porphyrin Complexes

用金属卟啉络合物引发合成高分子量聚醚

The Synthesis of High Molecular Weight Polyether Initiated by Metalloporphyrin Complex

非对称金属卟啉的合成及其紫外－可见光谱研究

Synthesis of a new nonsymmetrical metal porphyrin and its UV-vis spectra

因此，负载金属卟啉有其特定的必要性。

Therefore , it is necessary to study on supported metalloporphyrins .

血红素蛋白模拟（Ⅱ）&尾式噻吩基金属卟啉的合成与表征

Simulation of hemoproteins (ⅱ)?? synthesis and characterization of thiophene tailed metalloporphyrins

卟啉和金属卟啉光学非线性吸收的溶剂影响

Effect of Solvent on Optical Nonlinear Absorption of Porphyrin and Metalloporphyrins

四-（邻/对氯苯基）金属卟啉的合成

Synthesis of tetra - ( o / p-chlorophenyl ) Metal Porphyrins

新型手性基团修饰的金属卟啉的合成及性质研究

Studies on the Synthesis and Characters of a Novel Chiral Metalloporphyrin

含长链酯基的两种卟啉-5-氟尿嘧啶化合物的合成及结构表征金属卟啉和二氢卟吩-5-氟尿嘧啶化合物的合成

Synthesis and Structural Characterization of Two Long Chain Ester-group Porphyrin-5-Fluorouracil Compounds

金属卟啉与小分子有机碱的轴向平衡研究

A study on axial balance of metal porphyrin and small molecular bases