三氟甲磺酸酯

在微波辐射下，以NMP（1-甲基-2-吡啶酮）为溶剂，芳基三氟甲磺酸酯可与胺反应生成芳胺。

Aryl triflates were effectively converted to the corresponding anilines under the irradiation of microwave in the absence of base or catalyst by using NMP ( 1-mehyl-2-pyridone ) as a solvent .

计算结果表明，叠氮化物在二烷基三氟甲磺酸酯的作用下，不仅能够比较好的得到预期产物，而且反应条件温和，在室温下反应能发生。

The calculating results show that the azide under the effect of dialkyl triflate , not only be able to better obtain the desired product and the restrictions on the reaction conditions are more flexible , such as reacting at room temperature .

方法3′O（二苯膦酰氧）甲基缩醛核苷（1）在三甲基硅三氟甲磺酸酯（TMSOTf）条件下，与3′位保护的脱氧核苷（2或6）缩合。

Methods In the presence of trimethylsilyl trifluoromethane-sulfonate ( TMSOTf ), condensation of 3 ′ - O - ( diphenylphosphinyloxy ) methyl acetal ( 1 ) with 3 ′ - protected deoxynucleoside ( 2 or 6 ) afforded dimers ( 3 ) or trimers ( 7 ) respectively .