统计热力学

利用统计热力学中的微扰理论推算实际气体p、v、T的新方法

Calculation of p , v , t of real fluid using the perturbation theory of statistical thermodynamics

水泥石C-S-H凝胶的统计热力学基础

The Basis of Statistical Thermodynamics of C-S-H Gel in Hardened Cement Pastes

本文以统计热力学中的微扰理论为基础，建立一种推算实际气体p、v、T的新方法。

Based on the perturbation theory , a new method to calculate the p , v , T of real fluid is introduced .

利用基于经典热力学与统计热力学理论构建的模型，对聚合物中不同的CO2质量分数对应的玻璃化转变温度值进行了计算，得到的计算结果与实验结果较吻合。

The calculation results of T_g with different CO_2 content by using the theoretical model , which is based on classical and statistical thermodynamics agrees well with the experimental result .

αFe-N体系的统计热力学分析

Statistical thermodynamics of α fe-n system

借助统计热力学方法和正规溶液模型法估计了在αFe-N体系中氮原子与其周围最近邻氮原子之间的相互作用。

The interaction energy of N-N pairs in α Fe-N system was evaluated through statistical thermodynamics and regular solution model .

在特征晶体模型下，结合合金统计热力学，研究了Au-Cu系的热力学性质。

Applying statistic thermodynamics based on the characteristic crystal model , the thermodynamic properties of Au-Cu system have been studied .

基于统计热力学方法和Eyring的绝对反应速率理论求得该反应的热力学和动力学参数。

Finally , the thermodynamic and kinetic parameters have been investigated based on the statistical thermodynamics and transition state theory .

从统计热力学出发，通过对Flory-Huggins高分子溶胀平衡模型添加-SO3H与水作用项，获得一个三参数质子交换膜&水汽吸收模型。

A three-parameter sorption model of water vapor uptake in the Proton Exchange Membrane ( PEM ) is discussed here , derived from the Flory-Huggins model of polymer solution swell-equilibrium .

在一个大气压和298.15K的条件下用统计热力学的计算方法来计算负焓变，其结果显示整个包合是一个熵焓驱动过程。

The negative enthalpy changes calculated from the statistical thermodynamic calculations at 1 atm and 298.15K suggest that the inclusion complexes are favored enthalpy-driven processes .

用统计热力学方法在200～1100K范围内计算了某些大里德伯（Rydberg）分子的热力学函数以及电离过程的热力学函数改变值；

He changes of thermodynamic functions for ionization process of some large Rydberg molecules are calculated with statistical thermodynamic method over the temperature range of 200 ~ 1100K .

在量化计算的基础上运用统计热力学和Wigner校正的Eyring过渡态理论研究了不同温度下单重态CCl2和臭氧O3反应的热力学及动力学性质。

The thermodynamic and kinetic studies have been carried out on the reaction of singlet CCl2 and ozone O3 at 200K - 2000K , using statistic thermodynamics and Eyring transition state theory with Wigner correction on the basis of quantum chemistry .

纯液体表面张力的统计热力学模型

Statistical thermodynamic model for calculation of surface tension of pure liquids

由改进的方阱位能模型径向分布函数的解析式，结合统计热力学的方法关联纯物质的表面张力。

A modified square well analytical radial distribution function was derived .

统计热力学偶势超稳定性证明

Proof of the Superstability of pair potentials in statistical thermodynamics

非电解质液体混合物表面张力的统计热力学模型

Statistical thermodynamic model of surface tension for nonelectrolyte liquid mixtures

熔渣的化学统计热力学模型的应用

A molten slag model based on chemical statistical thermodynamics and Its Applications

物理化学中统计热力学的教学探讨

The Teaching of " the statistical thermodynamics " in the Physical Chemistry

介绍与宏观平衡现象相联系的统计热力学方面的知识。

Introduces aspects of statistical thermodynamics as they relate to macroscopic equilibrium phenomena .

二元及三元离子交换体系的统计热力学

Statistical Thermodynamics of Binary and Ternary Ion Exchange Systems

半刚性链分子的统计热力学（Ⅰ）

Statistical Thermodynamics of Semi - rigid Chain Molecules (ⅰ)

那么今天，我仅仅想继续探讨，一些统计热力学问题。

So today , I just want to continue doing some statistical thermodynamics .

加压下纯流体表面张力的统计热力学模型

A statistical thermodynamic model of surface tension for pure fluids at high pressure

嵌入式化合物嵌锂电压的统计热力学

Statistic thermodynamics study on intercalation voltage of inserted compound

液体的内压和内能的统计热力学理论

Inner Pressure and Inner Energy of the Liquid

高分子平衡熔点的统计热力学及相关分子能量参数的估算

Statistical Thermodynamics of Equilibrium Melting Points of Polymers and Estimation of Related Interaction Parameters

木材比热的统计热力学研究

On Specific Heat of Wood by Statistical Thermodynamics

液体内聚能的统计热力学研究

Statistical Thermodynamic Study on Cohesive Energy of Liquids

高分子混合体系相分离行为的统计热力学研究

Thermodynamics of Phase Behaviors for Polymer Fluids

计算液态混合物内能和内压的统计热力学理论

Statistical Thermodynamic Theory of Calculating the Inner Pressure and Inner Energy of the Liquid Mixture