配离子

某些Au（Ⅲ）、Au（Ⅰ）配离子在溶液中扩散的研究

Study on the Diffusion of Some Au (ⅲ) and Au (ⅰ) Complexes in Solution

Cd~（2+）-H2O系羟合配离子配位平衡

Equilibrium of hydroxyl complex ions in Cd ~ ( 2 + ) - H_2O system

成矿元素的助溶剂主要为CO2，其配合物主要为氯配合物，这些助溶剂和配离子均来自壳幔深部。

Auxiliary agent of ore-forming elements was mainly CO2 , and mineralizing agent was Cl - , and all of them were came from the crust-mantle .

PdCl4~（2-）配离子插层类水滑石的组装及其结构特征

Assembly and Structural Characterization of PdCl_4 ~ ( 2 - ) - Intercalated LDHs

论无氰铵盐（NH4Cl）镀锌溶液中配离子的组成

Approach to the composition of the complex ion in the zinc - plating solution of ammonium salt ( nh_4 ci ) free from cyanides

在碱性介质中，用分光光度法研究了二过碘酸合铜（Ⅲ）配离子（DPC）氧化1,3-丙二醇（PG）的反应动力学及机理。

Kinetics and mechanism of oxidation of 1 , 3-propylene glycol ( PG ) by diperiodatocuprater (ⅲ)( DPC ) in aqueous alkaline medium have been studied by spectrophotometry in a temperature range of ( 298.2 ~ 313.2 K ) .

铜氨配离子的空间构型初探

Research into the Configuration or Copper (ⅱ) and Ammonia Complex Ions

弱酸性溶液中葡萄糖酸锌配离子形态的研究

In weak acidity solution the study for the formula of zinc gluconate coordination ions

硝酸铈丙氨酸配合物的合成及其配离子的标准生成焓

Synthesis of Cerium Nitrate with Alanine Complex and Standard Molar Formation Enthalpy of Its Ion

竞争反应与配离子稳定性

Competition Reaction and Complex Ion Stability

实验也证实了铬配离子是与明胶分子中的羧基结合。

Furthermore , the experiment also confirmed that chrome complex reacted with the carboxyl of gelatin .

钯（Ⅱ）氯配离子在一些化学反应中的两种反应现象与机理

Two different phenomena and mechanisms of PdCl_4 ~ ( 2 - ) in some chemical reactions

讨论竞争反应平衡常数，并用其判断配离子在能与中心离子或配位体发生反应的溶液中的稳定性。

Based on the studies about the reaction mechanism , the conclusion can be made that some competitive reactions take place in plasma degradation process of oxygen .

对晶体和碱性介质中过渡金属超常氧化态配离子的主要存在形式和反应活化中心进行了综述，参考文献63篇。

The main existence of transition metals in highest oxidation state complex in crystalloid and alkaline medium and reaction activation center has been reviewed with 63 references .

结果表明温度越低，加质子常数和配合物稳定常数值都更高，说明温度越低，配离子稳定性越大或形成的配合物越难离解。

The results showed that the lower temperature , the higher plus proton constant and stability constant . It also indicated that the lower temperature , the more stable compound .

提出最高轨道数法，不仅能准确地推测分子型分子的构型，也能推测出自由基、分子型离子、以及配离子的构型，还能分析得出中心原子等性或不等性杂化类型。

In this paper , Highest Obital Figure Rules is introduced , which can not only accurately infer the structures of molecular type free radicals , molecular type ions and complex ions , but also analyse the hybridization type of the equality and inequality of the central atom .

季铵盐类配位离子液体的合成与表征

Synthesis and Characterization on Quaternary Ammonium Salt of Coordinated Ionic Liquids

磺基水杨酸铁（Ⅲ）配位离子的组成和稳定常数测定的微型实验

The micromation of the determination of the composition and the stable constant of sulfosalicylic acid iron (ⅲ) complex ion

结果表明随着熔渣中四配位离子的增加，其体相粘度增加，而六配位离子的作用则相反。

Results show that an increase of ions with 4-coordination number in molten slag makes the bulk viscosity increasing , while that with 6-coordination number is contrary .

根据化学热力学原理和配合物化学理论，研究了在化学镀镍溶液中，配位离子在沉积过程中的动态演变及沉积行为。

The theories of coordination chemistry and thermodynamic calculation , are applied to investigate the dynamic speciation and deposition behavior of the nickel complex in the electroless nickel solution during plating .

它们的结构差异说明：非配位金属离子的存在对配合物结构也产生影响。

Their structural diversity indicates that the presence of non-coordinative metal ion affects the CPs ' structures .

目的建立测定六神丸中脂蟾毒配基的离子抑制色谱分析法。

Purpose To establish a method for the determination of resibufogenin in Liushen pills by ion suppression chromatography .

Cr，Ca∶Y3Al5O（12）晶体中四配位四价铬离子激光中心的形成

Four-coordinated Cr ~ ( 4 + ) Laser Center in Cr , Ca : Y_3Al_5O_ ( 12 ) Crystal

首次采用以改性纤维素为基质、亚氨二乙酸（IDA）为取代配基的铜离子螯合膜色谱法对牛肝过氧化氢酶（BLC）的分离纯化进行了研究。

Cu 2 + chelating membrane medium based on iminodiacetate substituted modified short cotton cellulose was examined to purify bovine liver catalase ( BLC ) by affinity chromatography .

研究结果表明，MIP技术反应过程中，催化循环链的引发主要是原料中烷烃质子化，产生五配位正碳离子，使链反应遵循单分子的质子化裂化反应机理。

The results indicated that the main initiating event was the generation of a penta-coordinated carbonium ion by the protonation of paraffin in the feedstock , and the following reactions took place via monomolecular mechanism .

为计入离子电荷对流体混合物Helmholtz自由能的影响，作者考虑了位于中性分子的第一配位圈中离子的电荷与此分子的诱导偶极和偶极的相互作用。

The influence of ion charge on the Helmholtz energy of fluid mixtures was taken into account by considering the interactions between the charge of ions located in the first coordination shell and the dipole or induced dipole of the central solute molecule .

分别对采用物理共混法、自由基聚合、配位聚合和离子聚合法制备宽分子量分布聚合物进行了综述。

This paper reviewed the methods for preparing polymers having broad molecular weight distribution via physical blending , radical polymerization , coordination polymerization and ionic polymerization , respectively .

离子液体的咪唑阳离子对金属中心的弱配位性及离子液体的极性均有利于稳定催化反应中间体，提高了催化剂的催化活性及稳定性。

It was found that weak complexation between the imidazolium cations and meter centre of phosphotungstic acid and polarity of the ionic liquid moieties are conducive to stabilizing reaction inter-mediate .

根据配位化学热力学平衡原理，绘制了Cd2+-H2O系配合离子浓度pcpH图、镉羟合配离子分率αnpH图及Cd（OH）2条件溶度积pKSpH图。

The diagrams for the concentration of complex ions pc pH , the ratio of cadmium hydroxy complex ions α n pH and the conditional solubility product of Cd ( OH ) 2 to pH value in Cd2 + - H2O system were drawn , respectively .

饱和烃C-H键的活化及其配位催化反应的研究Ⅲ.PtCl4~（2-）配位离子催化戊烷氧化氯化反应的EHMO计算

Activation of C-H bond in alkanes and their coordinated catalytic reaction by organometallic complexes ⅲ . EHMO calculation of oxidative chlorination of pentane catalysed by ptcl_4 ~ ( 2 - ) ion